Home/Compounds/Research Reagent/Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
C48H40O4P2Ru
843.8 g/mol
Research ReagentDanger
Bisacetato[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphin]]ruthenium(II)
CAS325146-81-4EC689-262-0
Category
Research Reagent
Compound Class
Organometallic
Primary Use
Research Compound
This compound is a ruthenium-based chiral catalyst used in asymmetric hydrogenation reactions. It consists of a binaphthyl diphosphine ligand coordinated to ruthenium, with acetate groups present.
chiral catalyst for asymmetric hydrogenation
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CAS 325146-81-4
Related Compounds
StrongStructure SimilarSimilarity 1.00
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II)
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StrongStructure SimilarSimilarity 1.00
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
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StrongStructure SimilarSimilarity 1.00
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StrongStructure SimilarSimilarity 1.00
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Safety Reference
Danger
H228Flammable solid
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
H413May cause long lasting harmful effects to aquatic life
Identifiers
IUPAC Name
acetic acid;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium
InChIKey
XANQJWCSQJDBEA-UHFFFAOYSA-N
SMILES
CC(=O)O.CC(=O)O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Ru]
Synonyms (11)
- (R)-Ru(OAc)(BINAP)
- (R)-Ru(OAc)2(BINAP)
- (S)-Ru(OAc)2(BINAP)
- Ru(BINAP)(OAc)2