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Home/Compounds/Research Reagent/Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
C54H46Cl2P2Ru
928.9 g/mol
Research ReagentDanger

(S)-RuCl[(p-cymene(BINAP)Cl

CAS145926-28-9EC631-328-8
Category
Research Reagent
Compound Class
Organometallic
Primary Use
Research Compound

This compound is a ruthenium-based chiral complex used as a catalyst for asymmetric hydrogenation reactions. It combines a diphosphine ligand with a ruthenium center and is typically supplied as a research reagent for laboratory-scale synthesis.

asymmetric hydrogenation catalystresearch reagent for chiral synthesis

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

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CAS 145926-28-9

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Related Compounds

StrongSame Parent

CIS-((S)-BINAP)NI(O-TOLYL)CL

CAS1594113-05-9

research compound

StrongSame Parent

Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)

CAS212210-87-2

research compound

StrongSame Parent

(+)-BINAP

CAS76189-55-4

research compound

StrongSame Parent

(-)-BINAP

CAS76189-56-5

research compound

StrongStructure SimilarSimilarity 1.00

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

CAS325146-81-4

research compound

StrongStructure SimilarSimilarity 1.00

[Rh COD (R)-Binap]BF4

CAS120521-81-5

research compound

StrongStructure SimilarSimilarity 1.00

(S)-(-)-binap-chloro-(benzol)ruthenium-chloride

CAS126251-92-1

research compound

StrongStructure SimilarSimilarity 1.00

((S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium

CAS127593-28-6

research compound

Safety Reference

Flammable
Flammable
Corrosive
Corrosive
Harmful
Harmful
Environmental Hazard
Environmental Hazard
Danger
H228Flammable solid
H251Self-heating; may catch fire
H290May be corrosive to metals
H302Harmful if swallowed
H312Harmful in contact with skin
H332Harmful if inhaled
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
H413May cause long lasting harmful effects to aquatic life
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
Identifiers
IUPAC Name

dichlororuthenium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene

InChIKey

WNHLGYRPKARUHY-UHFFFAOYSA-L

SMILES

CC1=CC=C(C=C1)C(C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ru]Cl

Synonyms (13)
  • (R)-RuCl[(p-cymene)(BINAP)]Cl
  • (S)-RuCl[(p-cymene(BINAP)Cl
  • [rucl((r)-binap)(p-cymene)]cl