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Home/Compounds/Research Reagent/(R)-(+)-2,2'-Bis(diphenylphospino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl
C44H40P2
630.7 g/mol
Research ReagentWarning

(R)-H8-BINAP

CAS139139-86-9
Category
Research Reagent
Compound Class
Other
Primary Use
Research Compound

(R)-H8-BINAP is a chiral bisphosphine ligand, specifically the fully hydrogenated derivative of BINAP. It is widely employed as a chiral ligand in asymmetric catalysis to induce high enantioselectivity in transition-metal-catalyzed reactions.

chiral ligand for asymmetric hydrogenationchiral ligand for carbon-carbon bond-forming reactions

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

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Related Compounds

StrongSame Parent

(S)-(-)-2,2'-Bis(diphenylphospino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl

CAS139139-93-8

research compound

StrongSame Parent

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II)

CAS142962-95-6

research compound

StrongSame Parent

Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)

CAS204933-84-6

research compound

StrongSame Parent

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II)

CAS374067-51-3

research compound

ApplicationSame Use

(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(dicyclohexylphosphine)

CAS172617-14-0

research compound

ApplicationSame Use

(S)-5,5'-Bis(diphenylphosphino)-4,4'-bibenzodioxole

CAS210169-54-3

research compound

ApplicationSame Use

(1S)-1-(Diphenylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene

CAS155941-31-4

research compound

ApplicationSame Use

(S)-(-)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole

CAS210169-57-6

research compound

Safety Reference

Harmful
Harmful
Warning
H315Causes skin irritation
H319Causes serious eye irritation
Identifiers
IUPAC Name

[1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane

InChIKey

ANSOKCGDSQQISA-UHFFFAOYSA-N

SMILES

C1CCC2=C(C1)C=CC(=C2C3=C(C=CC4=C3CCCC4)P(C5=CC=CC=C5)C6=CC=CC=C6)P(C7=CC=CC=C7)C8=CC=CC=C8

Synonyms (17)
  • H8-BINAP
  • (R)-H8-BINAP
  • (S)-H8-BINAP

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