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Home/Compounds/Research Reagent/(S)-(-)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole
C46H44O4P2
722.8 g/mol
Research ReagentWarning

(S)-(-)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole

CAS210169-57-6EC811-356-9
Category
Research Reagent
Compound Class
Organometallic
Primary Use
Research Compound

This compound is a phosphine ligand featuring a 1,3-benzodioxole backbone, used as a chiral ligand in asymmetric catalysis. Its structure incorporates multiple aromatic rings and ether groups, contributing to its role in stereoselective synthesis.

chiral ligand for asymmetric catalysis

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

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Related Compounds

StrongSame Parent

(S)-(-)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole

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StrongSame Parent

[4-[5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl]-1,3-benzodioxol-5-yl]-bis(3,5-dimethylphenyl)phosphane;N-methylmethanamine;ruthenium;trichloronioruthenium(1-);chloride;hydrochloride

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StrongSame Parent

PUBCHEM_71310545

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StrongSame Parent

PUBCHEM_71310552

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ApplicationSame Use

SEGPHOS

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ApplicationSame Use

Iron(2+) bis{2-[bis(4-methoxy-3,5-dimethylphenyl)phosphanyl]-1-[(S)-(dimethylamino)(phenyl)methyl]cyclopenta-2,4-dien-1-ide}

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(S)-(+)-N,N-Dimethyl-1-[(2-diphenylphosphino)ferrocenyl]ethylamine

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(1S)-1-(Diphenylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene

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Safety Reference

Harmful
Harmful
Warning
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
Identifiers
IUPAC Name

[4-[5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl]-1,3-benzodioxol-5-yl]-bis(3,5-dimethylphenyl)phosphane

InChIKey

XJJVPYMFHXMROQ-UHFFFAOYSA-N

SMILES

CC1=CC(=CC(=C1)P(C2=C(C3=C(C=C2)OCO3)C4=C(C=CC5=C4OCO5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C

Synonyms (21)
  • (R)-(+)-DM-SEGPHOS(regR)
  • (R)-DM-SEGPHOS
  • (R)-DM-SEGPHOS(R)
  • (S)-(-)-DM-SEGPHOS(regR)
  • (S)-(-)-DM-SEGPHOS?
  • (S)-DM-SEGPHOS(R)