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Home/Compounds/Research Reagent/(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
C52H48P2
734.9 g/mol
Research ReagentWarning

(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL

CAS135139-00-3EC681-146-8
Category
Research Reagent
Compound Class
Organometallic
Primary Use
Research Compound

This compound is a sterically demanding bidentate phosphine ligand, specifically designed for use in asymmetric catalysis. Its significance lies in its role as a chiral ligand that can induce high enantioselectivity in transition-metal-catalyzed reactions, making it a standard tool in organic synthesis research.

chiral ligand for asymmetric hydrogenationligand for enantioselective cross-coupling reactions

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

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Related Compounds

StrongSame Parent

(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

CAS137219-86-4

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StrongSame Parent

Dichloro[(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)

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PUBCHEM_71310536

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StrongSame Parent

Dichloro[(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

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ApplicationSame Use

(1S)-1-(Diphenylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene

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ApplicationSame Use

(R)-(+)-2,2'-Bis(diphenylphospino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl

CAS139139-86-9

research compound

ApplicationSame Use

(S)-(-)-2,2'-Bis(diphenylphospino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl

CAS139139-93-8

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ReferenceSame Category

1-(4-Methoxybenzyl)-1,5,6,7-tetrahydro-4H-indazol-4-one

CAS1352907-89-1

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Safety Reference

Harmful
Harmful
Warning
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
Identifiers
IUPAC Name

[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane

InChIKey

MXGXXBYVDMVJAO-UHFFFAOYSA-N

SMILES

CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C

Synonyms (30)
  • DM-BINAP
  • (R)-(+)-XYLBINAP
  • (R)-3,5-XYLYL-BINAP
  • (R)-DM-BINAP
  • (S)-(-)-XYLBINAP
  • (S)-DM-BINAP
  • 3,5-Xylyl-BINAP