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Home/Compounds/Dye & Pigment/Benzidine
C12H12N2
184.24 g/mol
Dye & PigmentDanger

[1,1'-Biphenyl]-4,4'-diamine

CAS92-87-5EC202-199-1
Category
Dye & Pigment
Compound Class
Amine
Primary Use
dye intermediate for azo dyes

[1,1'-Biphenyl]-4,4'-diamine is a chemical compound primarily used as a dye intermediate in the production of azo dyes. It has significant applications in the leather, textile, and paper industries.

dye intermediate for azo dyesused in leather tanning and processingused in textile printing, dyeing, or finishing

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

Restricted or banned substances

Substances on this list are banned or restricted under the named regulation. This page is a compliance reference — verify your obligations under applicable law.

Relevant lists:EU REACH Restriction ListCalifornia Proposition 65

CAS 92-87-5

Related Compounds

StrongStructure SimilarSimilarity 1.00

4,4''-Diamino-p-terphenyl

CAS3365-85-3

research intermediate

StrongStructure SimilarSimilarity 1.00

P,p'-Diaminoquaterphenyl

CAS53693-67-7

research reagent

SimilarStructure SimilarSimilarity 0.79

1,3,5-Tris(4'-aminophenyl)benzene

CAS118727-34-7

research compound

SimilarStructure SimilarSimilarity 0.73

Terphenyl-4-amine

CAS7293-45-0

electronic chemical

ApplicationSame Use

4-hydroxy-7-(phenylamino)naphthalene-2-sulfonic acid

CAS119-40-4

dye intermediate for azo dyes

ReferenceSame Category

2-naphthylamine-6-sulfonic acid

CAS93-00-5

intermediate for azo dyes

ReferenceSame Category

2-naphthol-6-sulfonic acid

CAS93-01-6

Azo dye intermediate

ReferenceSame Category

N,N-diethyl-p-phenylenediamine

CAS93-05-0

Dye intermediate and photographic developer

Safety Reference

Harmful
Harmful
Health Hazard
Health Hazard
Environmental Hazard
Environmental Hazard
Danger
H302Harmful if swallowed
H350May cause cancer
H400Very toxic to aquatic life
H410Very toxic to aquatic life with long lasting effects
H341Suspected of causing genetic defects
H372Causes damage to organs through prolonged or repeated exposure
H373May cause damage to organs through prolonged or repeated exposure
H401Toxic to aquatic life
H411Toxic to aquatic life with long lasting effects
Regulatory Compliance3
  • EU REACH Restriction ListEURegulation
    RestrictedSource
  • California Proposition 65USRegulation
    Listed· listed since 1987-02-27Source
  • CN Catalogue of Hazardous ChemicalsCNRegulation
    Listed· listed since 2015-05-01Source

Customs Tariff Classification

The international HS code for [1,1'-Biphenyl]-4,4'-diamine (CAS 92-87-5) is 2921.59, 3824.99.

HS code (international, 6-digit)

2921.59, 3824.99

EU CN code (8-digit)

2921 59 90, 3824 99 92, 3824 99 93

Classification per the EU customs inventory ECICS (2026-07 snapshot, HS 2022). National tariff lines and product form can affect the final classification.

Identifiers
IUPAC Name

4-(4-aminophenyl)aniline

InChIKey

HFACYLZERDEVSX-UHFFFAOYSA-N

SMILES

C1=CC(=CC=C1C2=CC=C(C=C2)N)N

Synonyms (51)
  • Phenylbutazone EP Impurity E
  • 4,4'-Bianiline
  • 4,4'-Biphenyldiamine
  • 4,4'-Biphenylenediamine
  • 4,4'-Diamino-1,1'-biphenyl
  • 4,4'-Diaminobiphenyl
  • 4,4'-Diaminodiphenyl
  • 4,4'-Diamonophenyl
  • 4,4'-Diphenylenediamine
  • 4,4-Benzidine
  • 4-(4-aminophenyl)aniline
  • 4-(4-aminophenyl)phenylamine
  • Benzidin
  • Benzidin [Czech]
  • Benzidina
  • Benzidina [Italian]
  • Benzidine
  • Benzidine [UN1885] [Poison]
  • Benzidine base
  • Benzidine, >=98.0% (N)
  • Benzioine
  • Benzydyna
  • Benzydyna [Polish]
  • Biphenyl, 4,4'-diamino-
  • Biphenyl,4'-diamino-
  • Biphenyl-4,4'-ylenediamine
  • Fast Corinth Base B
  • PHENYLBUTAZONE IMPURITY E
  • Phenylbutazone Impurity A
  • [1,1'-Biphenyl]-4,4'-diamine
  • [1,4'-diamine
  • biphenyl-4,4'-diamine
  • p,p'-Diaminobiphenyl
  • p,p'-Dianiline
  • p,p'-diaminodiphenyl
  • p,p-Bianiline
  • p-Benzidine
  • p-Diaminodiphenyl