C13H13IO8
424.14 g/mol
Research ReagentDanger
Dess-Martin periodinane
CAS87413-09-0EC672-328-8
Category
Research Reagent
Compound Class
Other
Primary Use
Research Compound
Dess-Martin periodinane (DMP) is a chemical reagent used for the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones. It is valued for its mild reaction conditions, high chemoselectivity, and long shelf life, though its cost and potentially explosive nature limit industrial-scale use.
Oxidizing reagent for alcohol oxidation in organic synthesisSelective oxidation of sensitive functional groups in research
Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.
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CAS 87413-09-0
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Safety Reference
Danger
H272May intensify fire; oxidizer
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
Identifiers
IUPAC Name
(1,1-diacetyloxy-3-oxo-1lambda5,2-benziodoxol-1-yl) acetate
InChIKey
NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES
CC(=O)OI1(C2=CC=CC=C2C(=O)O1)(OC(=O)C)OC(=O)C
Synonyms (37)
- DESS-MARTIN PERIODINE
- Dess-Martin PeriodinaneDMP
- Dess-Martin Reactant
- Dess-Martin periodane
- Dess-Martin periodinane
- Dess-Martin's reagent
- Dess-Martine periodinane
- Dessmartin's periodinane
- MARTIN'S REAGENT
- REAGENTS, MARTIN'S
- dess martin
- dess-martin reagent
- desss-martin periodinane
- triacetoxy periodinane