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Home/Compounds/Research Reagent/[Rh COD (R)-Binap]BF4
C52H44BF4P2Rh
920.6 g/mol
Research Reagent

[Rh COD (R)-Binap]BF4

CAS439801-50-0
Category
Research Reagent
Compound Class
Organometallic
Primary Use
Research Compound

[Rh COD (R)-Binap]BF4 is a chiral organometallic compound featuring a rhodium center coordinated with (R)-BINAP and 1,5-cyclooctadiene ligands, and tetrafluoroborate as the counterion. It is widely used as a catalyst in asymmetric hydrogenation and other enantioselective transformations in organic synthesis.

Catalyst for asymmetric hydrogenationCatalyst for enantioselective carbon-carbon bond formationChiral catalyst for research in organometallic chemistry

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

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Related Compounds

StrongStructure SimilarSimilarity 1.00

(+)-BINAP

CAS76189-55-4

research compound

StrongStructure SimilarSimilarity 1.00

(-)-BINAP

CAS76189-56-5

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StrongStructure SimilarSimilarity 1.00

BINAP

CAS98327-87-8

research compound

StrongStructure SimilarSimilarity 1.00

[Rh COD (R)-Binap]BF4

CAS208118-82-5

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Identifiers
IUPAC Name

(1Z,5Z)-cycloocta-1,5-diene;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;rhodium;tetrafluoroborate

InChIKey

NXRNGSUCQWUDOA-ONEVTFJLSA-N

SMILES

[B-](F)(F)(F)F.C1/C=C\CC/C=C\C1.C1=CC=C(C=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C45)P(C6=CC=CC=C6)C7=CC=CC=C7)C8=CC=CC=C8.[Rh]

Synonyms (5)
  • [Rh COD (R)-Binap]BF4
  • [Rh COD (S)-Binap]BF4
  • [Rh COD (S)-Binap]BF4, Rh
  • [Rh COD (rac)-Binap]BF4