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Home/Compounds/Research Reagent/Tetrakis[N-phthaloyl-(R)-tert-leucinate]dirhodium
C64H72N4O20Rh2
1423.1 g/mol
Research Reagent

Rhodium(2+) (2R)-2-(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)-3,3-dimethylbutanoate--ethyl acetate (1/2/1)

CAS380375-05-3
Category
Research Reagent
Compound Class
Organometallic
Primary Use
Research Compound

This compound is a rhodium-based coordination complex used as a catalyst for asymmetric synthesis. It features a chiral ligand derived from tert-leucine and phthalimide, forming a dirhodium tetracarboxylate structure.

catalyst in asymmetric C-H insertion reactionscatalyst for enantioselective cyclopropanationcatalyst for carbene transfer reactions

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

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Related Compounds

SimilarStructure SimilarSimilarity 0.75

Tetrakis((2S)-2-(1,3-dioxobenzo[de]isoquinolin-2-yl)-3,3-dimethylbutanoate);bis(rhodium(2+))

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Referencestereoisomer of

Tetrakis[N-phthaloyl-(S)-tert-leucinato]dirhodium

CAS154090-43-4

research compound

Identifiers
IUPAC Name

tetrakis((2R)-2-(1,3-dioxoisoindol-2-yl)-3,3-dimethylbutanoate);ethyl acetate;bis(rhodium(2+))

InChIKey

WEPQIXHMGRKMPK-SVWMVHQSSA-J

SMILES

CCOC(=O)C.CCOC(=O)C.CC(C)(C)[C@H](C(=O)[O-])N1C(=O)C2=CC=CC=C2C1=O.CC(C)(C)[C@H](C(=O)[O-])N1C(=O)C2=CC=CC=C2C1=O.CC(C)(C)[C@H](C(=O)[O-])N1C(=O)C2=CC=CC=C2C1=O.CC(C)(C)[C@H](C(=O)[O-])N1C(=O)C2=CC=CC=C2C1=O.[Rh+2].[Rh+2]

Synonyms (2)

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