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Home/Compounds/Research Reagent/Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
C48H40O4P2Ru
843.8 g/mol
Research ReagentDanger

Bisacetato[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphin]]ruthenium(II)

CAS261948-85-0EC689-262-0
Category
Research Reagent
Compound Class
Organometallic
Primary Use
Research Compound

This compound is a ruthenium-based chiral hydrogenation catalyst, commonly supplied as an acetic acid adduct. It is primarily used in asymmetric synthesis for the enantioselective reduction of prochiral substrates.

enantioselective hydrogenation catalyst in asymmetric synthesisreagent for chiral reduction reactions in laboratory research

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

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Related Compounds

StrongStructure SimilarSimilarity 1.00

[Rh COD (R)-Binap]BF4

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StrongStructure SimilarSimilarity 1.00

(S)-(-)-binap-chloro-(benzol)ruthenium-chloride

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StrongStructure SimilarSimilarity 1.00

((S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium

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StrongStructure SimilarSimilarity 1.00

Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II)

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pharmaceutical intermediate

ApplicationSame Use

[Rh COD (R)-Binap]BF4

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Ru(OAc)2[(R)-dtbm-segphos]

CAS1025477-38-6

research compound

ReferenceSame Category

4-Methyl-3-(trifluoromethyl)benzoic acid

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ReferenceSame Category

6-Iodo-1H-indazole

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Safety Reference

Flammable
Flammable
Harmful
Harmful
Environmental Hazard
Environmental Hazard
Danger
H228Flammable solid
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
H413May cause long lasting harmful effects to aquatic life
Identifiers
IUPAC Name

acetic acid;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium

InChIKey

XANQJWCSQJDBEA-UHFFFAOYSA-N

SMILES

CC(=O)O.CC(=O)O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Ru]

Synonyms (11)
  • (R)-Ru(OAc)(BINAP)
  • (R)-Ru(OAc)2(BINAP)
  • (S)-Ru(OAc)2(BINAP)
  • Ru(BINAP)(OAc)2