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Home/Compounds/Research Reagent/Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
C54H46Cl2P2Ru
928.9 g/mol
Research ReagentDanger

(S)-RuCl[(p-cymene(BINAP)Cl

CAS130004-33-0EC631-328-8
Category
Research Reagent
Compound Class
Organometallic
Primary Use
Research Compound

This compound is a ruthenium-based asymmetric hydrogenation catalyst, commonly used in research and development for the synthesis of enantiomerically enriched compounds. It features a chiral diphosphine ligand coordinated to ruthenium, enabling high selectivity in reduction reactions.

Asymmetric hydrogenation catalyst for chiral synthesisResearch reagent for enantioselective reduction

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

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Related Compounds

StrongStructure SimilarSimilarity 1.00

Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II)

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(S)-(-)-binap-chloro-(benzol)ruthenium-chloride

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StrongStructure SimilarSimilarity 1.00

((S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium

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Safety Reference

Flammable
Flammable
Corrosive
Corrosive
Harmful
Harmful
Environmental Hazard
Environmental Hazard
Danger
H228Flammable solid
H251Self-heating; may catch fire
H290May be corrosive to metals
H302Harmful if swallowed
H312Harmful in contact with skin
H332Harmful if inhaled
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
H413May cause long lasting harmful effects to aquatic life
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
Identifiers
IUPAC Name

dichlororuthenium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene

InChIKey

WNHLGYRPKARUHY-UHFFFAOYSA-L

SMILES

CC1=CC=C(C=C1)C(C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ru]Cl

Synonyms (13)
  • (R)-RuCl[(p-cymene)(BINAP)]Cl
  • (S)-RuCl[(p-cymene(BINAP)Cl
  • [rucl((r)-binap)(p-cymene)]cl