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Home/Compounds/Industrial Chemical/O-tolidine
C14H16N2
212.29 g/mol
Industrial ChemicalDanger

O-Tolidine

CAS119-93-7EC204-358-0
Category
Industrial Chemical
Compound Class
Amine
Primary Use
Intermediate for dyes and pigments

o-Tolidine (3,3'-dimethylbenzidine) is an industrial chemical used primarily as an intermediate in the production of dyes and pigments. It is also employed as a curing agent for polyurethane elastomers and coatings, and as a sensitive reagent for detecting gold and free chlorine in water.

Intermediate for the production of dyes and pigmentsCuring agent for polyurethane elastomers, coatings, and rigid foamsReagent for detection of gold and free chlorine in water

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

Restricted or banned substances

Substances on this list are banned or restricted under the named regulation. This page is a compliance reference — verify your obligations under applicable law.

Relevant lists:California Proposition 65

CAS 119-93-7

Related Compounds

StrongSame Parent

O-tolidine dihydrochloride

CAS612-82-8

dye intermediate and reagent

ApplicationSame Use

1,2,4-Benzenetriamine dihydrochloride

CAS615-47-4

Intermediate for dyes and pigments

ApplicationSame Use

4-chloro-2-aminophenol

CAS95-85-2

Intermediate for dyes and pigments

ReferenceSame Category

Di-n-butylmagnesium

CAS1191-47-5

Grignard reagent precursor

ReferenceSame Category

Cyclobutanone

CAS1191-95-3

Chemical intermediate for synthesis

ReferenceSame Category

2,3-dihydrofuran

CAS1191-99-7

chemical intermediate

ReferenceSame Category

2,4-Dichlorobromobenzene

CAS1193-72-2

Industrial chemical intermediate

Safety Reference

Harmful
Harmful
Health Hazard
Health Hazard
Environmental Hazard
Environmental Hazard
Danger
H302Harmful if swallowed
H350May cause cancer
H411Toxic to aquatic life with long lasting effects
H372Causes damage to organs through prolonged or repeated exposure
H373May cause damage to organs through prolonged or repeated exposure
H341Suspected of causing genetic defects
H401Toxic to aquatic life
H351Suspected of causing cancer
Regulatory Compliance2
  • California Proposition 65USRegulation
    Listed· listed since 1988-01-01Source
  • CN Catalogue of Hazardous ChemicalsCNRegulation
    Listed· listed since 2015-05-01Source

Customs Tariff Classification

The international HS code for O-Tolidine (CAS 119-93-7) is 2921.59.

HS code (international, 6-digit)

2921.59

EU CN code (8-digit)

2921 59 50

Classification per the EU customs inventory ECICS (2026-07 snapshot, HS 2022). National tariff lines and product form can affect the final classification.

Identifiers
IUPAC Name

4-(4-amino-3-methylphenyl)-2-methylaniline

InChIKey

NUIURNJTPRWVAP-UHFFFAOYSA-N

SMILES

CC1=C(C=CC(=C1)C2=CC(=C(C=C2)N)C)N

Synonyms (46)
  • 2-Tolidin
  • 2-Tolidin [German]
  • 2-Tolidina
  • 2-Tolidina [Italian]
  • 2-Tolidine
  • 3,3'-DIMETHYLBENZIDINE
  • 3,3'-Dimethylbenzidin
  • 3,3'-Tolidine
  • 4,4'-Bi-o-toluidine
  • 4,4'-Bianisidine
  • 4,4'-Di-o-toluidine
  • Benzidine, 3,3'-dimethyl-
  • Bianisidine
  • DIMETHYLBENZIDINE, 3,3'-
  • Diaminoditolyl
  • Diaminotolyl
  • Fast Dark Blue Base R
  • Orthotolidine
  • Tolidine, o-
  • o,o'-Tolidine
  • o-Tolidin
  • o-Tolidine
  • o-Tolidine, >=97%, powder
  • o-Tolidine, Powder, Reagent
  • o-Tolidine, minimum
  • o-Tolidine, p.a.
  • tolidine blue