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Home/Compounds/Research Reagent/Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
C52H48O4P2Ru
899.9 g/mol
Research ReagentWarning

(S)-Ru(OAc)2(T-BINAP)

CAS116128-29-1EC634-602-5
Category
Research Reagent
Compound Class
Organometallic
Primary Use
Research Compound

This compound is a ruthenium-based complex coordinated with a chiral bisphosphine ligand and acetate groups, primarily used as a catalyst in asymmetric hydrogenation reactions.

Asymmetric hydrogenation catalyst

Content scope: Information here supports chemical identification and industrial supply, research, and manufacturing contexts. It is not a therapeutic claim, medical advice, or drug-use instructions.

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CAS 116128-29-1

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Related Compounds

StrongSame Parent

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride

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StrongSame Parent

Dimethylammonium dichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)

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(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl

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(S)-2,2'-Bis[bis(4-methylphenyl)phosphino]-1,1'-binaphthyl

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Safety Reference

Harmful
Harmful
Warning
H319Causes serious eye irritation
H335May cause respiratory irritation
Identifiers
IUPAC Name

acetic acid;[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;ruthenium

InChIKey

OXESSJMVRGFBNX-UHFFFAOYSA-N

SMILES

CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.CC(=O)O.CC(=O)O.[Ru]

Synonyms (8)
  • (R)-Ru(OAc)2(T-BINAP)
  • (S)-Ru(OAc)2(T-BINAP)
  • RU(OAC)2[(R)-TOLBINAP]
  • RU(OAC)2[(S)-TOLBINAP]